The Different Types of E-Bike Batteries
There are two newer battery technologies on the horizon and one of them is beginning to be featured in some e-bikes. One type is lithium-iron-phosphate (LiFePO4), which we will take a look at after we examine solid state batteries, because solid-state batteries share more in common with lithium-ion batteries.
The Electric Bike Report team is thrilled at what’s to come from new battery tech, but there’s some interesting things already happening now with different types of e-bike batteries. Let’s explore them all, shall we?
What is a solid-state battery?
A solid-state battery is, in fact, a lithium-ion battery, but by another name. Why have a different name? Its construction and materials used are slightly different. Both batteries feature an electrolyte solution. Okay, but what are electrolytes?
Electrolytes are minerals (generally in the form of salts), that can carry an electrical charge. Electrolytes help move the electrical charge that causes a muscle to contract in people. Think Gatorade.
In a lithium-ion battery, that electrolyte solution is a liquid and it helps conduct ions in both the anode (the + or positive end of the battery) and the cathode (- or negative end of the battery). The anode and cathode are separated by a barrier between the two ends of the battery. The issue with this technology is that should that barrier between the anode and cathode be ruptured, a chemical reaction can begin that can result in thermal runaway, the process that results in lithium-ion batteries catching fire. Also, the main ingredient (by volume) in the liquid electrolyte is ethylene carbonate, which is flammable and produces toxic gasses when burned.
By contrast, a solid-state battery uses a solid electrolyte throughout the battery. This form of electrolyte is more stable and won’t swell due to temperature change or experience thermal runaway like a traditional lithium-ion battery.
Aside from the safety benefits that come a solid-state battery, there are additional selling points to this technology. The first, biggest is that a solid-state battery offers increased capacity because it doesn’t need a thick membrane separating the anode and cathode of the battery. So, more charge, same physical space.
How much more energy capacity can a solid-state battery offer over lithium-ion? It’s hard to say, unfortunately. That’s because of a wide range of battery capacities. The technical term for this capacity is called “specific energy,” and it is expressed as watt/hours per kilogram (Wh/Kg). On the low end, a lithium-ion battery may offer only 75Wh/Kg, though most range between 150 and 200Wh/Kg. At the high end, the current iPhone 14 contains a lithium-ion battery with a 250Wh/Kg energy density.
By comparison, solid-state batteries are being produced that offer 350-400Wh/Kg. Depending on the battery in question, that’s at least double the specific energy, but potentially as much as four times as much energy. .
What that means is that an e-bike with a battery that currently weighs 8 lbs. could conceivably see it replaced by a battery that weighs half as much, but offers twice the capacity.
The second big advantage is that solid-state batteries enjoy a longer life cycle, meaning they can be charged and discharged more times.
More is good, but that’s not terribly specific, so let’s quantify that some. The average lithium-ion battery can be charged around 2000 times. Some handle closer to 3000 cycles. By comparison, a solid-state battery may offer as many as 10,000 cycles before needing to be replaced.
Solid-state batteries will also benefit from far shorter charging times, with some batteries being able to reach 80 percent charge in 10 minutes and 100 percent in 15.
A look inside lithium-iron-phosphate technology
The first selling point for lithium-iron-phosphate battery technology is greater safety. They lack the combustible lithium-cobalt-oxide cathode, which is combustible. When a lithium-ion battery is overcharged and heat begins to build up, and results in thermal runaway, it is the lithium-cobalt-oxide anode that catches fire.
Lithium-iron-phosphate batteries perform well in abusive situations, such as in high temperatures, or in rapid charging.
And while contents of lithium-ion batteries are considered hazardous materials, which presents issues when the battery reaches the end of its effective life, lithium-iron-phosphate batteries are nontoxic.
Lithium-iron-phosphate batteries are not only less expensive (and easier) to dispose of, they are less expensive to make, in part because they lack any toxic materials workers must be protected from.
The major drawback for lithium-iron-phosphate batteries is that their specific energy (Wh/Kg) is roughly two-thirds that of lithium-ion. If typical lithium-ion batteries offer a specific energy of 150-200Wh-Kg, the common range for lithium-iron-phosphate batteries is only 90-120Wh/Kg.
What this means is that they make poor substitutes for lithium-ion batteries in handheld or portable electronics where the higher the specific energy, the more valuable the battery.
What this means for e-bikes
Despite the promise of no chance for thermal runaway and easy post-use processing, lithium-iron-phosphate batteries are unlikely to make a big dent in the e-bike world because of their low specific energy numbers. Cutting a battery’s specific energy by one third means that to give a lithium-iron-phosphate battery the same capacity as a lithium-ion battery, it would have to weigh a third more, so that 6-lb., 672Wh battery would have to weigh 8 lbs. in order to offer that same 672Wh capacity.
Such a weight penalty makes this technology one the e-bike industry is likely to avoid.
Solid-state lithium-ion batteries make for a very different proposition, however.
It’s easy to see how a technology that has the ability to double or triple the specific energy of a battery would grab the attention of engineers working in e-bikes. That it offers greater safety and a longer life makes the technology such an improvement on existing lithium-ion batteries it’s easy to wonder why we haven’t seen them on e-bikes yet.
The game-changer
So when will we begin to see solid-state lithium-ion batteries? The wait may not be long, but it’s not over … quite yet.
The Swiss e-bike maker Stromer recently showed off a solid-state lithium-ion-ceramic battery. This battery isn’t in production yet, but they have a rideable prototype.
Working with TD Hitech Energy, a Taiwanese battery maker, Stromer’s specifications call for a battery that can charge at temperatures as low as -22 degrees Fahrenheit and charge at a rate as high as 5C—about 12 minutes. Currently, their prototype will charge at -4 degrees Fahrenheit and will charge at 3C—roughly 20 minutes.
There’s no word yet on what the capacity of this battery is, but because this is Stromer, which is a premium e-bike brand that prides itself on making some of the longest-range e-bikes on the market (one of their models comes with a battery that can assist a rider to cover up to 160 mi. on a single charge), this is a technology that they could use to increase range while simultaneously reducing e-bike weight.
What everyone wants to know is when we will begin to see solid-state batteries on e-bikes. We are likely years away. Stromer estimates we may see a solid-state battery on their e-bikes as soon as 2025. Again, Stromer occupies the high-end of the e-bike market, and with the extra cost involved to produce these batteries, we are likely to see them on high-end eMTBs long before we see them on any consumer-direct e-bikes for some years to come.
Consumers who want to make the transition to riding an e-bike with a solid-state battery are likely to be faced with a choice. For the impatient among us, a new e-bike purchase may be unavoidable. That’s because until factories ramp up production of these batteries, they are likely to be in short supply. E-bike makers would rather sell new e-bikes than upgrades to existing e-bikes, which means that there will be a delay of several years before we begin seeing solid-state batteries offered at aftermarket.
Chow-chi Huang says
For wider operating temperature range, more charge cycles (5-7X), ability to use 100% vs 60-80% (recommended use range for most ternary chemistries is 20-80% of full capacity, with occasional extension to 20-100% for long trips) of its capacity and lower likelihood of thermal runaway, I’d gladly accept a LFP battery that weighs 2lbs more than my current ternary lithium battery. That 2lbs is a tiny fraction of my total weight (ebike, me, tools, accessories, locks) of around 320lbs.
This is an important issue, one the industry of PEVs has been too slow to address.
One point about the role of insurance you alluded to for PEV companies is they are already influencing landlords, which is already impacting sales and use of PEVs. Many landlords or property management companies have issued blanket bans on PEVs in or even near their properties due to the greater costs of insurance. They are not discriminating by UL certification or not, at least for now. This is due to the lack of proactive action to address the issue of cheap, dangerous equipment. It will take time, data and convincing by manufacturers and retailers to change this direction.
Kevin says
100% agree. In fact, it is not debatable.
This was obviously written by someone with a skewed POV. The fact that LFP is much safer is worth the extra 2lbs on a typical 670Whr ebike, which are typically 65lbs plus in total already. Add in the fact that LFP lasts 2 to 3 times longer than lithium-ion and it is a no-brainier.
LFP batteries are also cheaper than lithium-ion. The ebike industry will be moving to LFP for the majority of ebikes. Lithium-ion will still be used for high-end light ebikes. Their are other reasons why LFP batteries have not already taken over E-transportation (cars, bikes,..) but that is changing.
The US is pushing for UL Certification to make the ebike batteries safer. They need to be pushing for LFP.
I hope solid state makes it but it is a long way off and very expensive. For the next decade plus let’s stick to reality. Sodium-Ion shows promise in ebike applications sooner as well.
Tom says
Thanks for publishing this article. The solid state battery technology will first show up in cell phones, tablets, and laptops since that market is thousands of times bigger than the ebike market. And everyone wants a lighter cell phone with a longer battery life, that charges quicker.
King Karlos Delgado the Great says
How big would a new solid starlte battery have to be for 750 v, watts? Idk if I’m trying to fig out volts or watts ..which ones need to be 500 or more to make a motorcycle do 100 mph? Honestly id be happy with a top end of 80 mph plus I’m a light dude. So what size and cost will I be looking at for one of them new solid state battery to get me one compatible with the current dirt bikes size 125? I know 125 refers to CC and that’s gas dirt bikes but idk what else to say to describe a 125 dirt bike… /Adult pit bike 😯